Most questions answered within 4 hours. Calculate the pH of a 0.0010 M solution of acetic acid, \(K_a = 1.74 \times 10^{5}\). What is the H3O+ concentration? Stack Exchange network consists of 181 Q&A communities including Stack Overflow, the largest, most trusted online community for developers to learn, share their knowledge, and build their careers. [7], Based on mammalian median lethal dose (LD50) rating of 2,660mg/kg body mass, boric acid is only poisonous if taken internally or inhaled in large quantities. Dissociation of NaCl. This page titled 13.7: Exact Calculations and Approximations is shared under a CC BY 3.0 license and was authored, remixed, and/or curated by Stephen Lower via source content that was edited to the style and standards of the LibreTexts platform; a detailed edit history is available upon request. As with many boron compounds, there is some question about its true nature, but for most practical purposes it can be considered to be monoprotic with \(K_a = 7.3 \times 10^{10}\): \[Bi(OH)_3 + 2 H_2O \rightleftharpoons Bi(OH)_4^ + H_3O^+\nonumber \]. [43] Boric acid largely spares lactobacilli within the vagina. You'll get a detailed solution from a subject matter expert that helps you learn core concepts. What makes "water with electrolytes" distinct from other forms of water? (https://en.wikipedia.org/wiki/Boric_acid#Properties) In accordance with the triprotic model three separate university websites (North Carolina State University, University of California Santa Barbara, and the University of Washington) cited the Ka1 of boric acid to be 5.8 x 10-10. Making educational experiences better for everyone. This can be indicated a forward arrow to show the reaction going to completion. You'll get a detailed solution from a subject matter expert that helps you learn core concepts. By increasing boric acid concentration in the reactor coolant, the probability that a neutron will cause fission is reduced. How do you explain the relatively high conductivity of tap water compared to a low or. Pellentesque dapibus efficitur laoreet. \[[H^+]^3 +(C_b +K_a)[H^+]^2 (K_w + C_aK_a) [H^+] K_aK_w = 0 \label{5-8a}\], In almost all practical cases it is possible to make simplifying assumptions. Why is acid added to the water not the water to the acid? Thus if the solution is known to be acidic or alkaline, then the [OH] or [H+] terms in Equation \(\ref{5-8}\) can be neglected. Note: Using the Henderson-Hassalbach Approximateion (Equation \(\ref{5-11}\)) would give pH = pKa = 1.9. Explain on this answer, would you expect them to dissociate? How are stearic acid molecules aligned on the water surface to produce a monolayer? On the other hand, a conjugate base is what is left over after an acid has . Nam lacinia pulvinar tortor n
sectetur adipiscing elit. & \text{$\ce{H3BO3}$} & \text{$\ce{H3O+}$} & \text{$\ce{H2BO3-}$} \\ (See the green box below for more on this.). H3BO3H3BO2-+ The ammonium ion is the conjugate acid of the base ammonia, NH 3; its acid ionization (or acid hydrolysis) reaction is represented by. Hi Jenny Ann. Textile fiberglass is used to reinforce plastics in applications that range from boats, to industrial piping to computer circuit boards.[31]. As the acid concentration falls below about 106 M, however, the second term predominates; \([H^+]\) approaches \(\sqrt{K_w}\) or \(10^{7} M\) at 25 C. It can also be noted that boric acid is sparingly soluble in pyridine and slightly soluble in acetone. (3) For H3PO4 and H3BO3, does the subscript "3" of hydrogen in these two formulas seem to result in additional ions in solution as it did in Group A? Most acids are weak; there are hundreds of thousands of them, whereas there are no more than a few dozen strong acids. Is NH3(aq) an electrolyte or a non-electrolyte? Put your understanding of this concept to test by answering a few MCQs. Does cobalt(II) chloride dissolved in water possess electrical conductivity? Explain. Very dilute solutions of boric acid can be used as an eyewash. Boric acid, H3 BO3, is a triprotic acid that dissociates in three reactions. Carbonated water is a solution of carbonic acid (H2CO3). You want to use a 0.500 M HNO3 solution to titrate an unknown concentration of KOH solution. Since ammonia is a weak base, Kb is measurable and Ka > 0 (ammonium ion is a weak acid). Furthermore, it is of vital importance to regulate the fluid viscosity that helps to keep the grains of the propping agents suspended for long transport distances in order to keep the cracks in the shales sufficiently open. Select the correct answer and click on the Finish buttonCheck your score and answers at the end of the quiz, Visit BYJUS for all Chemistry related queries and study materials, Your Mobile number and Email id will not be published. .H3PO3 ==> H^+ + H2BO3^- Solved Boric acid (H3BO3) dissociates in water following the - Chegg
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